In view of the problem that most existing network situation prediction methods are unable to mine the deep information in the data and need to manually extract and construct features, a deep feature network situation prediction method named DFS-Seq2Seq (Deep Feature Synthesis-Sequence to Sequence) was proposed. First, the data produced by network streams, logs and system events were cleaned, and the deep feature synthesis algorithm was used to automatically synthesize the deep relation features. Then the synthesized features were extracted by the AutoEncoder (AE). Finally, the data was estimated by using the Seq2Seq (Sequence to Sequence) model constructed by Long Short-Term Memory (LSTM). Through a well-designed experiment, the proposed method was verified on the public dataset Kent2016. Experimental results show that when the depth is 2, compared with four classification models including Support Vector Machine (SVM), Bayes, Random Forest (RF) and LSTM, the proposed method has the recall rate increased by 7.4%, 11.5%, 6.5% and 3.0%, respectively. It is verified that DFS-Seq2Seq can effectively identify dangerous events in network authentication and effectively predict network situation in practice.